May 28, 2017

Biology : Chemistry of life

Elements and atoms

  • Proton : defines the element. the numbers of protons in the nucleus of the atom defines. 
  • # of protons = atomic number = what  defines elements
  • For example, Hydrogen has one proton, helium has two protons.. 
  • Electron
  • Neutron
  • proton and neutron in the center of the atom=nucleus of the atom
  • Neutron can change, electron is change, the atom is still the same atom. 
  • protons cannot change. 
  • protons have positive charge.
  • electrons have negative charge.
  • they attract each other.
  • isotope : the same element with a different of neutrons

Electron shells and orbitals

Orbitals

  • the Bohr model : model electrons as planets revolving around a star
  • with more energy, its orbit will become more elliptical
  • as electrons gets more energy, it will enter the higher energy state
  • when eletrons get further away from a high energy state the coulomb force is weaker
  • then they're easier to pluck off
  • the electron configuration : the distribution of electrons of an atom or molecule (or other physical structure) in atomic or molecular orbitals.
  • Coulomb force : attraction or repulsion(=repel) of particles or objects because of their electric charge. 

More on orbitals and electron configuration

  • electrons fill up the orbitals from lowest energy state to high energy state
  • electron configuration for carbon : 1s2 2s2 2p(no 3s follows)
  • electron configuration for nitrogen : 1s2 2s2 2p3
  • electron configuration for silicon : 1s2 2s2 2p6 3s2 3p2
  • 2p6 it filled up of this p-block over here(from B to Ne)
  • 3p2 in the third periond+second row of the p block

Valence electrons and bonding

  • valence electrons = electrons that atom will use to when it react
  • valence electrons : tends to be with highest energy level/furthest out from the center(for s and p block, not for transition metals )
  • in the same group elements : are going to have same # of Valence eletron
  • Carbon's electron configuration is [He]2s2 2p2
  • How many electrons does it have in its outermost shell=not been completed yet
  • These four [He]2s2 2p2
  • in carbon's group, they are all going to have 4 Valence electrons
  • covalent bond : 
  • Fe(iron)'s electron configuration with Ar(argon) as a base = [Ar] 4s2 3d6
  • transition metals
  • D block : known as transition metals(bridge between s-block and p-block)
  • F block : known as inner transition metals(bridge between s-block and d-block)

Groups of the periodic table

  • the most part the elements in the column(group) have very similar properties\
  • and same bonding behavior
  • because they tend to have the same number of electrons in their outermost shell(=same # of valence electrons)
  • group 1, alkali metals(except for Hydrogen), very reactive(one valence electron left to react)
  • group 2, alkaline earth metals, 2 valence electrons in their the outermost shell, reasonably reactable
  • electron configuration for Sc : [Ar] 4s2 3d1(backfill)
  • group 17, Halogen, love to react with alkali metals
  • group 18, noble gases(=atomic nirvana), have similar properties not being reacted
  • because they have 8 valence electron, filled their outermost shell
  • octet rule : Most of the elements important in biology need eight electrons in their outermost shell in order to be stable
  • Subshells are designated by the letters s, p, d, and f, and each letter indicates a different shape
  • each orbital can hold up to two electrons. p subshell has 3 dimensions then it can hold up to 6 electrons at most. 
  • d orbital, but this orbital is considerably higher in energy than the 3s and 3p orbitals and does not begin to fill until the fourth row of the periodic table

Chemical bonds and reactions

  • Ionic, covalent, and metallic bonds
  • ionic bond : not sharing electrons, just handed over electrons, then attracted force is coming(due to different charges)
  • ionic bond forms ion. cation(positive charge), anion(negative charge)
  • covalent bond : is a chemical bond that involves the sharing of 2 electrons between atoms. (when atoms aren't very different in terms of their electronegativity)
  • polar covalent bond : one side of the molecule is going to be more negative/positive 
  • non polar covalent bond : form between two atoms of the same element, so between atoms of different elements that share electrons equally.
  • metallic bond : they love to share electrons, make a pool of electrons, which make them malleable(easy to bend)

Electronegativity

  • Electron affinity : how much does the atom attract electrons
  • Electronegativity : high or low electron density. when that atom is part of a covalent bond, how likely does it want to hog(keep) electrons in that covalent bond? 
  • in case of H2O, oxygen is more electronegativity, so electrons spend more time around oxygen
  • (on groups)from left to right, it is more electronegative
  • (on period)from top to bottom, it is less electronegative. because atoms on the bottom have more shells, so the electron in the furthest shell is easier to grab off(give up the electron)

Electronegativity and bonding 

  • Pauling scale for electronegativity
  • Oxygen is more electronegative than carbon, it is partially negative.(meanwhile, carbon is partially positive)=polarized situation. polar covalent bond.
  • <->non-polar covalent bond
  • if the difference of electronegativity more than 0.5, consider to be polar covalent bond
  • in case of Na-Cl, the difference of electronegativity(2.1) so big, they're not gonna share electrons. Cl steals electrons. 
  • Cl gets former negative charge, Na gets former positive charge=the ionic bond
  • if the difference of electronegativity more than 1.7, consider to be ionic bond
  • those numbers(0.5 and 1.7) are not absolute. 

Intermolecular forces

  • means forces between molecules
  • dipole-dipole interaction(acetone molecule)
  • oxygen(partially +), carbon(partially -)=two different poles=polar molecule
  • there's going to be an electrostatic attraction between O(from molecule A) and C(from molecule B)
  • its intermolecular force holds molecules as a liquid at room temperature.
  • it depends on the electronegativity.
  • hydrogen bonding(water molecule) : stronger version of dipole-dipole, the strongest intermolecular force(O-H-O)
  • it need more energy to pull these water(boiling temp. 100'c) molecule apart than acetone(boiling temp. 56'c) 
  • FON : fluorine, oxygen, nitrogen = electronegative atoms participate in hydrogen bonding
  • london dispersion focrces(methane) : the weakest intermolecular force
  • van der Waals forces : a general term for intermolecular interactions that do not involve covalent bonds or ions

Chemical reactions

  • reactants->products
  • coefficients : a number of moleculs participate in the reaction
  • the law of conservation of matter : Equations must be balanced
  • reversible reactions : to the state of equilibrium
  • cation : positively charged ion
  • anion : negatively charged ion

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